Coal desulfurization has been regarded as an effective pretreatment for clean fuel and less environmental pollution. The microwave irradiation was used to desulfurize the Nantong coal leached with H 2 O 2 and NaOH. The results showed the desulfurization rate of the coal is very low by directly microwave irradiation, while the coal samples leached with H 2 O 2 and NaOH by microwave irradiation ...
How to reduce the energy consumption of the rotary kilnelectric furnace (RKEF) process has become an important issue for the stainless steel industry. The aim of this study is to reduce the energy consumption of ferronickel production from saprolite nickel laterite in the RKEF process. The effects of the slag binary basicity, FeO content, and Cr2O3 content on the melting temperature and ...
An anodic electrolytic oxidation desulphurization experiment was carried out on the liquefaction residue of the byproduct of a coaltoliquid enterprise in the slurry state. An electrochemical test and material characterization of raw materials before and after electrolysis showed that electrolytic oxidation can desulfurize the liquefaction ...
This process, termed MoltenCausticLeaching, or the Gravimelt Process, results in removal of 9099% of the coal inorganic and organic sulfur as well as 9599% of the coal mineral matter. The product coal meets all current air pollution control standards for sulfur and ash emissions, and has an increased heat content, usually in the ...
In this study, coal fly ash was functionalized, using a simple onestep process (loading with Al3+ and sulfonation), to yield a solid acid catalyst (S/AlCFA) with strong acid sites. The catalyst was then used to produce furfural from xylose in a biphasic system (H2O(NaCl)/tetrahydrofuran). The furfural yield reached 82% at 180 °C60 min with catalyst/xylose ratio of : (w/w).
In the flue gas ammonia desulfurization process of the coal chemical industry, ammonium sulfate slurry in the desulfurization tower often s and overflows, which wastes resources and pollutes the environment. The solution to this problem remains largely unknown. This paper aims to reveal the causes of ing by analyzing composition, ammonia desulfurization process raw material source ...
The second part examines recent advances in desulphurization techniques and future challenges for commercial, that are being researched around the world and are regulating the manufacture of a new ...
The FlueGas Desulfurization (FGD) process utilizes a set of technologies to remove sulfur dioxide (SO 2) from the flue gas emissions of coalfired power systems were developed as a response to the exhaust flue gases from fossil fuelburning plants, principally coalburning, that posed both an environmental and human health hazard.
Since the "Eleventh FiveYear Plan" period, the construction of flue gas desulfurization and denitrification facilities for coalfired power plants have been accelerated to control the emissions of sulfur dioxide (SO 2) and nitrogen oxides (NO X) and thus to address the issue of acid rain in to the goal of the "Thirteenth FiveYear Plan for Energy Saving and Emission ...
Therefore, exhaust gas from burning process with high sulphur coal must be treated by installations for removal of SO 2. Due to the high cost of these installations and under the increasing limitations of SO 2 emissions, predesulphurization of coal is essential.
The flue gas desulfurization wastewater is highly saline and has too many refractory pollutants to be recycled during the desulfurization process of the coalfired heating plant. Given that waste heat is abundant in coalfired heating plants, a thermal ...
Most of the effective coal desulfurization techniques are based on chemical methods. Main desulfurization methods are chemical desulfurization, leaching, extraction, flotation, oxydesulfurization and biodesulfurization. The alkaline desulfurization is more effective in removing the pyritic sulfur from the coal, which is the less abundant form ...
In this pretreatment process, the coal layer thickness and length of stay in the reaction cavity should be controlled, the sulphurcontaining gases within the cavity should be exported timely, and it should be ensured that the temperature of the coal sample after pretreatment was 150250 °C. ... (1996) Microwave desulphurization of coal ...
The selectivity of a facile reductive and extractive desulfurization process was studied. In this desulfurization method, polyethylene glycol was used as the extractant, and sodium borohydride was ...
Fly ash, which is a solid waste from coal power plants, was used as a precursor to prepare a zeolitetype adsorbent. This fly ashbased zeolite (Gismondine) was active for desulfurization of a model feed of TH (500 ppm S) and BT (500 ppm S) with 43% and % sulfur removal efficiency [125]. Dolochar is a waste byproduct of the sponge iron ...
Coal is a nonrenewable fossil fuel and has been used as a main source of energy for centuries. Fossil fuels are utilized as not only for energy production but also the raw material as the main inputs for many industries such as paint, plastic, pharmaceutical, cosmetics, iron steel and aluminum production (Prayuenyong 2002).However, the use of coal, both the energy source of some of the major ...
A process flow diagram for the HDS plant is shown in Fig. 1. Desulfurization reactions take place in fixed bed catalytic reactors (∆ R) where a minimum ratio H 2 /hydrocarbon must be ensured for catalyst maintenance reasons. Reactors are fed with a blend of fuels of different qualities. The hydrocarbon (HC) feed is mixed with the recycled H 2 stream (R) and with makeup H 2 from the network.
Abstract. Through the purification technology of flue gas desulfurization, ultralow emissions of SO2 flue gas in industrial flue gas can be achieved. This article involves dry desulfurization, semidry desulfurization, and wet desulfurization technologies. The research progress of these technologies since they were first proposed is summarized ...
In this work, the desulfurization process of highsulfur anthracite coal is discussed, and the desulfurization method of "reduced iron powder + heat treatment + magnetic separation" (named "RIHM") is designed. The effects of the heating temperature, heating time and coaliron mass ratio on desulfurization were discussed, the process of ...
A new multiphase noncatalytic process is developed for deep desulphurization of fuels or organics using hydrodynamic cavitation with vortex diode as a cavitating device. The process can ...
![Desulfurization of coal using four ionic liquids with [HSO4]−](/yt3sdqe/353.jpg)
The combined irradiation process of ultrasonic and microwave energy is observed to be the most effective for the beneficiation of highsulfur coal than the single process. The result showed a maximum of % and % ash (mineral matter) removal from the coal samples by microwave followed by an ultrasonic process.
Pyrolysis desulfurization is suitable for coal. By changing the coking conditions to promote the effusion of sulfide in the form of gas. According to the pyrolysis conditions, it can be divided into pyrolysis desulfurization under atmosphere and copyrolysis desulfurization with additives [40], [41], [42]. Up to now, pyrolysis desulfurization ...
The major coal desulphurization technologies prior to combustion are physical coal cleaning, chemical and biological methods. Each has some technical and economical limitations. Physical coal cleaning can only remove limited amount of inorganic sulphur due to insufficient liberation. Fine grinding can liberate fine pyrites, where novel coal ...
The flue gas desulfurization process in coalfired power plants is energy and resourceintensive but the ecoefficiency of this process has scarcely been considered. Given the fluctuating unit load and complex desulfurization mechanism, optimizing the desulfurization system based on the traditional mechanistic model poses a great challenge. In this regard, the present study optimized the eco ...
N2 The paper proposed a twostep desulphurization process using ironbased high temperature sorbents for removal of hydrogen sulfide from hot coal gases after coal gasification. The authors use the mixture of iron oxide with other metal oxides ( Ce) supported by ash from a coalgangue fired power plant to prepare high temperature ...
Coal combustion is the largest single source of sulfur oxide pollution. Treatment of some major representative coals with aqueous ferric solution removes 40 to 75 percent of the sulfur content through near quantitative oxidation of the pyritic sulfur contained in the coal matrix. Elemental sulfur and iron sulfate are recovered as products ...
A novel method for the chemical desulfurization of coal in relatively moderate conditions and short times is presented. Using concentrated hydroiodic acid as a desulfurizing agent and microwaves as the energy source, sulfate and pyritic sulfur are completely removed in 10 min. Moreover, for the lowrank coals studied, variable amounts of organic sulfur, up to 70% in 20 min, can be removed, for ...
"There's a major issue around captive coal power stations in Indonesia, that runs the risk of derailing or slowing that JETP process," said Leo Roberts, an analyst at climate think tank E3G.
To further remove the total sulfur, this study applied the electrolysis process of coal in aqueous sodium chloride and sodium hydroxide (NaOH) solutions. The changes of sulfur forms were confirmed ...
With the increasingly prominent global energy and environmental problems, more and more enterprises have been required to desulfurize the exhausted gases. Different enterprises have different demands for the desulfurization process, thus the choice of desulfurization process methods has become a focus of attention. Since the evaluation of the desulfurization process involves many factors, this ...
article{osti_, title = {Coal desulfurization}, author = {Meyers, R A and Van Nice, L J and Santy, M J}, abstractNote = {The Meyers process of removing pyritic sulfur from coal chemically before it is burned is presented. The process involves the treatment of crushed coal with an aqueous leaching solution of ferric sulfate which reacts with the coal pyrites to yield soluable ferrous ...
According to the enlargement of fine particles by heterogeneous condensation and typical technology of wet flue gas desulphurization (WFGD) system, a novel process is proposed in this paper to remove fine particles from coalfired flue gas in WFGD system which use limestone as desulfurizer.
Sulfur in coal exists in inorganic and organic forms, the former being mostly pyritic sulfur. Total sulfur contents in major coalfields are in the range of roughly wt%. In coal combustion, to generate electric power and process heat, the sulfur is emitted as SO2, which is seen as one of the main causes of acid rain. This effect has led ...
environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. This work summarizes the desulfurization and denitration ... Desulphurization technology The existing flue gas desulfurization technologies in China include limestone gypsum wet process, ammonia process, magnesium oxide ...
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